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Home > Products >  Dess-Martin periodinane

Dess-Martin periodinane CAS NO.87413-09-0

  • Product Details

Keywords

  • 1,1-DIHYDRO-1,1,1-TRIACETOXY-1,2-BENZOIODOOXOL-3(1H)-ONE
  • 1,1-DIACETOXY-3-OXO-1L5-IODA-2-OXA-INDAN-1-YL ESTER
  • catalyst

Quick Details

  • ProName: Dess-Martin periodinane
  • CasNo: 87413-09-0
  • Molecular Formula: C13H13IO8
  • Appearance: white crystals
  • Application: Dess-Martin Periodinaneis a very usefu...
  • PackAge: 1g, 100g, 1kg, 10kg, 25kg
  • ProductionCapacity: 10 Kilogram/Week
  • Purity: 98%+
  • Storage: in tight, light resistant containers
  • LimitNum: 1 Gram

Superiority

Dess-Martin Periodinaneis a very usefulreagent used in the oxidation of primary alcohols to aldehydes and secondary alcohols to ketones.

Dess–Martin periodinane (DMP) is a chemical reagent used to oxidize primary alcohols to aldehydes and secondary alcohols toketones.[1][2] This periodinane has several advantages over chromium- and DMSO-based oxidants that include milder conditions (room temperature, neutral pH), shorter reaction times, higher yields, simplified workups, high chemoselectivity, tolerance of sensitive functional groups, and a long shelf life. It is named after the American chemists Daniel Benjamin Dess and James Cullen Martin who developed the reagent in 1983. It is based on IBX, but due to the acetate groups attached to the central iodine atom, DMP is much more reactive than IBX and is much more soluble in organic solvents.[3]

Reaction scheme

After several years of continuous development and optimization in synthesis route and process conditions, this product has gained approval from various customers from both domestic and overseas market. 

Details

Dess–Martin periodinane (DMP) is a chemical reagent used to oxidize primary alcohols to aldehydes and secondary alcohols toketones.[1][2] This periodinane has several advantages over chromium- and DMSO-based oxidants that include milder conditions (room temperature, neutral pH), shorter reaction times, higher yields, simplified workups, high chemoselectivity, tolerance of sensitive functional groups, and a long shelf life. It is named after the American chemists Daniel Benjamin Dess and James Cullen Martin who developed the reagent in 1983. It is based on IBX, but due to the acetate groups attached to the central iodine atom, DMP is much more reactive than IBX and is much more soluble in organic solvents.[3]

Reaction scheme

After several years of continuous development and optimization in synthesis route and process conditions, this product becomes a star product in our company. Its high and stable product quality has gained approval from various customers from both domestic and overseas market. 

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